Corn herbicide large seeded broadleaf weeds

Considerations for Residual Herbicides in Corn

Residual herbicides that kill weed seeds/seedlings as they germinate or emerge are an important component of herbicide applications at or before the time of corn planting.

These herbicides can control weeds for several weeks, which prevents yield loss due to early-season weed competition and can greatly improve the effectiveness of a post-emergence herbicide application and give more flexibility for post-application timing.

Residual herbicides are also an important component of sequential herbicide applications later in the growing season. In general, preventing the emergence of weeds, especially herbicide resistant weeds, is preferable to controlling them after they emerge (Figure 1).

Many cases of herbicide-resistant weeds have resulted from over-reliance on post-emergence herbicide applications, thus it is essential to include one or more residual herbicides available for corn. However, it is also important to remember to change residual herbicides to prevent selection of tolerant or resistant weeds.

The importance of this is reflected in the recent confirmation of waterhemp and Palmer amaranth that are resistant to S- metolachlor (Dual).

The specific herbicide you use is important, but it is usually less important than making the decision to use a residual herbicide. But, it is important to know the strengths and weaknesses of each product in terms of the spectrum of weeds controlled.

A table summarizing weed species response to various corn herbicides can be found on pages 24-26 of 2021 Chemical Weed Control for Field Crops, Pastures, Rangeland, and Noncropland (SRP 1162) at: https://bookstore.ksre.ksu.edu/pubs/SRP1162.pdf

Categories of Residuals for Corn

• Triazines (Group 5). Atrazine is the most widely used triazine in corn. It is a common component of many preplant and pre-emergence herbicide premixes for corn. It controls a wide variety of broadleaf weeds, including pigweeds, ragweeds, morningglories, and mustards, as well as some grass species. However, atrazine resistance has been reported for many weed species.

Atrazine use rates are influenced by soil type, soil pH, and organic matter, and use is prohibited in instances where water contamination is likely. Unless your situation prohibits atrazine use, it is recommended to include atrazine when you apply HPPD-inhibitor and acetamide herbicides.

• Acetamides and pyrazole (Group 15). The main acetamide (15) products used in corn include acetochlor, S-metolachlor, metolachlor, dimethamid-P, and many premix products containing one of these active ingredients. Pyroxasulfone is a pyrazole herbicide, but has the same site of action as the acetamides.

In general, these products are very effective in controlling most annual grasses (except shattercane) and small-seeded broadleaf weeds such as pigweeds. They are much less effective in controlling small-seeded kochia or large-seeded broadleaf weeds such as cocklebur, devilsclaw, morningglory, sunflower, and velvetleaf. An exception are those products containing pyroxasulfone, such as Zidua, Anthem, and Anthem ATZ, Fierce and Fierce MTZ.

Engenia Pro and Purpetuo are two other pyroxasulfone-containing products that are awaiting approval Though resistance to Group 15 herbicides have been reported in corn/soybean rotations in Illinois, there have been no cases of weed populations in Kansas developing resistance to the group 15 herbicides to date.

The acetamide and pyrazole products are most effective when applied with atrazine. Several such premixes are available and should be used instead of acetamides or pyrazole alone, unless atrazine is not allowed.

These premixes generally fit into two groups: products with a reduced atrazine rate (1 lb or less/acre) and products with a full atrazine rate (1 to 2 lb/acre).

Figure 1. The corn plot in the foreground received no pre-emergence herbicide. The plots adjacent to the untreated check received an application of pre-emergence herbicide.

Soil characteristics determine whether the reduced- or full-rate atrazine product is used. In past years, often because of cost, reduced rates of these products were applied to help manage heavy summer annual grass pressure, then followed up with a good post-emergence herbicide program.

With the increased occurrence of glyphosate- and other herbicide-resistant weeds, it is essential to use the full rates of these products in conjunction with a POST program.

• HPPD-inhibitors (Group 27). Examples of HPPD-inhibitors are isoxaflutole (e.g. Balance Flexx) and mesotrione (e.g. Callisto and many generics). These products should be applied with atrazine, which is often included in premixes with Group 27 herbicides (e.g. Acuron, Callisto Xtra, Lexar EZ, Lumax EZ).

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HPPD-inhibitors provide excellent for control of kochia, pigweeds, velvetleaf, and many other broadleaf weeds, as well as grasses. Corvus (thiencarbazone + isoxaflutole) will control shattercane and common sunflower better than Balance Flexx, provided the sunflower is not ALS-resistant.

Prequel has a low rate of Balance mixed with Resolve and will not provide the same level of residual weed control as Acuron, Resicore, Lexar EZ, Lumax EZ, Balance Flexx, or Corvus used at full rates. Keep in mind, products containing Balance should not be applied to coarse-textured soils when the water table is less than 25 feet below the soil surface. Balance Flexx does not provide adequate control of sunflower.

PPO-inhibitors (Group 14). Examples of PPO-inhibitors include flumioxazin (e.g. Valor) and saflufenacil (Sharpen (14). Herbicides containing flumiozaxin must be applied 7 to 30 days before corn planting. These herbicides provide excellent control of pigweeds; however, they are marginal on kochia. Fierce (flumioxazin + pyroxasulfone) will provide improved control of velvetleaf and kochia compared to Valor.

The addition of atrazine will enhance kochia, pigweed, velvetleaf, and morningglory control, provided the populations are not triazine-resistant. Sharpen and Verdict (saflufenacil + dimethenamid-P) have excellent activity on pigweeds, kochia, and large-seeded broadleaf weeds. However, the length of residual activity can be shorter than other pre-emergence products when all are compared at full rates. Approximately 7 to 10 days of residual can be expected per 1 oz of Sharpen and 5 oz of Verdict.

• ALS-inhibitors (Group 2). One example of a pre-emergence ALS-inhibitor used in corn is flumetsulam (Python), which only has broadleaf activity and provides good control of large-seeded broadleaf weeds such as cocklebur, sunflower, and velvetleaf, or the small-seeded common lambsquarters.

Flumetsulam is also a component of Hornet, Stanza, SureStart II, and TripleFlex II. These products are especially effective for control of sunflower, along with cocklebur and velvetleaf, but less effective for morningglory control.

Rimsulfuron is another ALS-inhibiting herbicide that is a component of Basis Blend, Instigate, Prequel, Realm Q and Steadfast Q. Products with rimsulfuron will provide short residual control of grass and broadleaf weeds and should be used as a setup herbicide with a good post-emergence weed control program. If ALS-resistant broadleaf weeds are present, these ALS-containing herbicides often will be less effective.

Pre-emergence herbicide programs for corn

Difficult weeds, especially glyphosate-resistant weeds, are controlled most consistently with soil-applied herbicides which kill germinating seeds/seedlings. Much of the resistance to glyphosate has developed from over-reliance on post-emergence herbicide applications for weed control. Thus it is essential to include one or more of the preplant and pre-emergence residual herbicides available for corn. The specific herbicide you use, although important, is usually less important than just making the decision to use a preplant or pre-emergence herbicide.

It is important to use multiple modes of action when selecting herbicides. To assist growers, we have included in this article a reference number in parentheses that corresponds to the herbicide’s site of action. For example, the reference number herbicide mode of action for glyphosate is No. 9, and will be referred to in this article as “glyphosate (9).” There is a key to all herbicide sites of action at the end of this article. When there are two or more numbers in parentheses, it means the active ingredients in a product have different modes of action. If a herbicide is mentioned more than once in a paragraph, we include the reference number only after the first mention of the product in that paragraph.

It is important to change herbicide programs from time to time so that you do not get hooked on any single herbicide program year after year. Weed species shift and develop resistance to herbicide programs that do not change. It’s also important to know the strengths and weaknesses of each product in terms of the spectrum of weeds controlled. A table summarizing weed species response to various corn herbicides can be found on pages 24-26 of 2019 Chemical Weed Control for Field Crops, Pastures, Rangeland, and Noncropland (SRP 1139) at: https://www.bookstore.ksre.ksu.edu/pubs/SRP1148.pdf

For burndown applications in a no-till system on emerged grass and broadleaf weeds, an application of glyphosate (9) and a product containing dicamba (4) or 2,4-D (4) may be critical. The choice between 2,4-D and dicamba will depend on weed species present. Dicamba products will be more effective on kochia and marestail. 2,4-D is more effective on winter annual mustards. The use of pre-emergence herbicides, applied just before or following planting, often provides control of weeds for several weeks. This can greatly improve the effectiveness of a post-emergence herbicide application, and gives the producer more leeway on post application timing.

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Categories of soil-applied residual herbicides for corn

Soil-applied residual herbicides for corn can be grouped into several basic categories.

Atrazine (5) is a common component of many preplant and pre-emergence herbicide premixes for corn. Where weed pressure is light, a March application of atrazine with crop-oil concentrate and 2,4-D (4) or dicamba (4) can control winter annual weeds such as mustards and marestail and provide control of most germinating weeds up to planting. If kochia is the key target, 0.5 to 1.0 lb/acre atrazine (5) with a pint of dicamba (4) applied in late February to early March can provide excellent control of germinating kochia. It is essential to add glyphosate (9) to the mix if winter annual grasses are present. In a premix with other herbicides, atrazine adds burndown control of newly emerged grasses and broadleaf weeds present near planting time, as well as some residual control of small-seeded broadleaf weeds such as pigweeds and kochia (except for triazine-resistant populations). Unless your situation prohibits atrazine use, always apply atrazine (5) with HPPD-inhibitor (27) and acetamide (15) herbicides.

Acetamides (15) and pyrazole (15) /atrazine (5) premixes. The main acetamide (15) products used in corn include acetochlor, S-metolachlor, metolachlor, dimethamid-P, and many premix products containing one of these active ingredients. The pyrozole products include Pyroxasulfone (15) is a pyrazole herbicide, but has the same site of action as the acetamides. In general, these products are very effective in controlling most annual grasses (except shattercane) and small-seeded broadleaf weeds such as pigweeds. They are much less effective in controlling small-seeded kochia or large-seeded broadleaf weeds such as cocklebur, devilsclaw, morningglory, sunflower, and velvetleaf. An exception are those products containing pyroxasulfone – Zidua (15), Anthem (15, 14), and Anthem ATZ (15, 14, 5). These products have activity on kochia and velvetleaf. There have been no cases of weed populations in Kansas developing resistance to the group 15 herbicides to date.

The acetamide and pyrazole products are most effective when applied with atrazine. Several atrazine (5) /acetamide or pyrazole (15) premixes are available and should be used instead of acetamides or pyrazole alone unless atrazine is not allowed. These premixes generally fit into two groups: products with a reduced atrazine rate (1 lb or less / acre) and products with a full atrazine rate (1 to 2 lb/acre). Soil type, soil pH, and organic matter will determine whether the reduced- or full-rate atrazine product is used. In past years, often because of cost, reduced rates of these products were applied to help manage heavy summer annual grass pressure, then followed up with a good post-emergence herbicide program. With the increased occurrence of glyphosate- and other herbicide-resistant weeds, it is essential to use the full rates of these products in conjunction with a POST program.

HPPD-inhibitors (27). Examples of HPPD-inhibitors are isoxaflutole (e.g. Balance Flexx (27), Corvus (27, 2), and Prequel (27, 2)) and mesotrione (e.g. Callisto and many Generic (27), Callisto Xtra (27, 5), Resicore (27, 15, 4), Acuron (27, 15, 5), Lexar EZ (27, 15, 5), Lumax EZ (27, 15, 5), Acuron Flexi (27, 15), Zemax (27, 15). These products either contain atrazine or should be applied with atrazine, and are excellent for control of kochia, pigweeds, velvetleaf, and many other broadleaf weeds.

Acuron (27, 15, 5), Lexar EZ (27, 15, 5), Lumax EZ (27, 15, 5), Resicore (27, 15, 4) and Corvus (17, 2)+atrazine (5) provide excellent control of grass weeds. Corvus will also control shattercane. Balance Flexx has activity on shattercane but is less consistent than Corvus. Prequel has a low rate of Balance mixed with Resolve and will not provide the same level of residual weed control as Acuron, Resicore, Lexar EZ, Lumax EZ, Balance Flexx, or Corvus used at full rates. Keep in mind, products containing Balance should not be applied to coarse-textured soils when the water table is less than 25 feet below the soil surface. Balance Flexx does not provide adequate control of sunflower. Corvus will be much better than Balance Flexx on sunflower, provided the sunflower is not ALS-resistant. Herbicides containing clopyralid (4) such as Hornet (4, 2), Resicore (15, 4, 27), TripleFlex II (15, 4, 2), or Surestart II (15, 4, 2) will also provide very good control of sunflower.

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A new herbicide from Syngenta called Acuron contains Lumax EZ (27, 15, 5) + bicyclopyrone (27). Bicyclopyrone is an HPPD-inhibitor herbicide that enhances large-seeded broadleaf weed control and also has grass activity. Acuron (27, 15, 5) provides enhanced control of giant ragweed, common ragweed, common cocklebur, and velvetleaf, along with improved morningglory control compared to Lumax EZ. Acuron Flexi (27, 15) is basically Acuron without atrazine. Acuron Flexi (27, 15) and Zemax (27, 15) (basically Lumax without atrazine (5)) were developed for areas where atrazine generally isn’t used or is prohibited. Resicore will also fit in this scenario and is the most effective of the non-atrazine products in this list. Zemax and Acuron Flexi, without the atrazine (5), may provide less broadleaf weed control.

PPO-inhibitors (14). Examples of PPO-inhibitors include flumioxazin (e.g. Valor (14), and Fierce (14, 15), and saflufenacil (Sharpen (14), and Verdict (14, 15). Valor or Fierce must be applied 7 to 30 days before corn planting in a no-till system. These herbicides provide excellent control of pigweeds; however, they are marginal on kochia. Fierce will provide improved control of velvetleaf and kochia compared to Valor. The addition of atrazine (5) will enhance kochia, pigweed, velvetleaf, and morningglory control, provided the populations are not triazine-resistant. Sharpen and Verdict have excellent activity on pigweeds, kochia, and large-seeded broadleaf weeds. However, the length of residual activity can be shorter than other pre-emergence products when all are compared at full rates. This will depend on the rates of Sharpen and Verdict used. Approximately 7 to 10 days of residual can be expected per 1 oz of Sharpen and 5 oz of Verdict.

ALS-inhibitors (2). Examples of ALS-inhibitors for use as a soil-applied herbicide for corn include flumetsulam, Python (2); and Hornet (2, 4), a premix of flumetsulam (2) and clopyralid (4). Both herbicides have broadleaf activity only. These products are strong on large-seeded broadleaf weeds such as cocklebur, sunflower, and velvetleaf, or the small-seeded common lambsquarters. Adding Hornet to a full rate of an acetamide (15) /atrazine (5) mix as a pre-emerge treatment will control the annual grasses and add considerably to large-seeded broadleaf weed control. Three-way premixes of acetochlor (15)+clopyralid (4)+flumetsulam (2), include SureStart II (15, 4, 2) and TripleFlex II (15, 4, 2). These products are especially effective for control of sunflower, along with cocklebur and velvetleaf, but less effective for morningglory control. Resicore (15, 4, 27) is a premix of acetochlor (15)+clopyralid (4)+ mesotrione (27). This product contains 3 modes of action as did SureStart II and TripleFlex II, only the ALS-inhibitor (2) has been replaced with an HPPD-inhibitor (27).

Rimsulfuron is another ALS-inhibiting (2) herbicide that is a component of Prequel (2, 27), Instigate (2, 27), Basis (2), and Basis Blend (2). Products with Rimsulfuron will provide short residual control of grass and broadleaf weeds and should be used as a setup herbicide with a good postemergence weed control program. If ALS-resistant broadleaf weeds are present, these ALS-containing herbicides often will be less effective.

Key to herbicide mode of action reference numbers

The Weed Science Society of America has developed a numbered classification system based on the herbicide site of action to assist farmers and applicators in selecting herbicides with different sites of action. Most herbicide labels now prominently display the herbicide classification number at the begin­ning of the label. Herbicide premixes that contain multiple active ingredients with different sites of action will have all sites of action numbers listed. The Take Action Herbicide Classification chart is an excellent reference that summarizes herbicide active ingredients and sites of action:

Dallas Peterson, Extension Agronomy State Leader and Weed Management Specialist
[email protected]